Triazenylphosphoranyl radicals undergo cyclisation to give paramagnetic phosphoranes and the rapid pseudo-rotation of the latter can be monitored by e.s.r. spectroscopy.
J. C. Brand and B. P. Roberts, J. Chem. Soc., Chem. Commun., 1981, 1107 DOI: 10.1039/C39810001107
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