trans-Cycloheptane was prepared at –78 °C by a singlet-sensitized photoisomerization of the cis-isomer, and its lifetime was measured at temperatures between –7.0 and +1.0 °C to give thermodynamic parameters for the thermal trans–cis isomerization: Ea= 18.7 kcal mol–1, log A= 12.2
Y. Inoue, T. Ueoka, T. Kuroda and T. Hakushi, J. Chem. Soc., Chem. Commun., 1981, 1031 DOI: 10.1039/C39810001031
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