An internal electron transfer process from ruthenium(II) to an octaethylporphyrin radical moiety is induced by changes in axial ligation, and the species formed by a two-electron oxidation of ruthenium(II) porphyrins is characterized as a ruthenium(III) porphyrin cation radical.
M. Barley, J. Y. Becker, G. Domazetis, D. Dolphin and B. R. James, J. Chem. Soc., Chem. Commun., 1981, 982 DOI: 10.1039/C39810000982
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