15  N Nuclear polarisation during nitro-group exchange reactions on a σ-complex formed by ipso-attack

Paul Helsby; John H. Ridd; John P. B. Sandall

doi:10.1039/C39810000825

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¹⁵N Nuclear polarisation during nitro-group exchange reactions on a σ-complex formed by ipso-attack

Paul Helsby, John H. Ridd and John P. B. Sandall

Abstract

The ¹⁵NO₂–¹⁴NO₂ exchange reactions of the ion (2) with nitric acid give rise to either enhanced absorption or emission in the ¹⁵N n.m.r. spectrum of the ion depending on the direction of the exchange.

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DOI: https://doi.org/10.1039/C39810000825
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1981, 825-827

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¹⁵ N Nuclear polarisation during nitro-group exchange reactions on a σ-complex formed by ipso-attack

P. Helsby, J. H. Ridd and J. P. B. Sandall, J. Chem. Soc., Chem. Commun., 1981, 825 DOI: 10.1039/C39810000825

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Journal of the Chemical Society, Chemical Communications