Issue 15, 1981

Oxygenation reactions of cytochrome oxidase models. Evidence for hematin formation in mononuclear and heterobinuclear complexes

Abstract

Controlled potential electrolysis, chemical reduction, or synthesis is used to prepare the FeIII/CuI and FeII/CuI complexes of meso-tetra-αααα-o-(nicotinami-dophenyl)porphyrin; on exposure to oxygen the Cu-free derivative and the fully reduced heterobinuclear complexes undergo irreversible oxidation to the hematins Fe(P)–OH–(N4) and Fe(P)–OH–Cu(N4)2+, respectively.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 799-801

Oxygenation reactions of cytochrome oxidase models. Evidence for hematin formation in mononuclear and heterobinuclear complexes

M. J. Gunter, L. N. Mander and K. S. Murray, J. Chem. Soc., Chem. Commun., 1981, 799 DOI: 10.1039/C39810000799

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