The structure of the triphenylphosphine–sulphur trioxide complex has been established by X-ray crystallography which shows that the complex contains a phosphorus–sulphur bond and demonstrates the way in which the sulphur atom is shielded by the three aromatic rings.
I. J. Galpin, G. W. Kenner, A. Marston and O. S. Mills, J. Chem. Soc., Chem. Commun., 1981, 789 DOI: 10.1039/C39810000789
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