A synthessis of the tricyclic sesquiterpene hydrocarbon (±)-hirsutene, involving a novel photo-thermal metathetic sequence as the key step to generate the linearly fused tricyclopentanoid framework, is reported.
G. Mehta and A. V. Reddy, J. Chem. Soc., Chem. Commun., 1981, 756 DOI: 10.1039/C39810000756
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