The unsaturated mixed-metal cluster anion [Os6Au(CO)20H2]– has been prepared as its [N(PPh3)2]+ salt by the reaction of [Os3Au(CO)10(PR3)H](R = Ph, Et) with [N(PPh3)2]Cl; its X-ray crystal structure shows that the AuI atom links two ‘Os3(CO)10H’ units via co-ordination to two short Os–Os bonds.
B. F. G. Johnson, D. A. Kaner, J. Lewis and P. R. Raithby, J. Chem. Soc., Chem. Commun., 1981, 753 DOI: 10.1039/C39810000753
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