The synthesis, separation, and solvolysis of the stereoisomeric dienynyl trifluoromethanesulphonates (1) are described, whereby the E-isomers, in contrast with the Z-isomers, rearrange to a remarkable extent to form the phenyl ethers (5)via the phenyl cations (2).
M. Hanack and W. Holweger, J. Chem. Soc., Chem. Commun., 1981, 713 DOI: 10.1039/C39810000713
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