When UO2 is oxidised to UO2+x a second ‘shake-up’ satellite is identified at 8·2 eV to the high binding energy side of each U 4f core level in the photoelectron spectrum; these satellites are attributed to the development of oxygen clusters in the UO2 lattice structure.
G. C. Allen, P. M. Tucker and J. W. Tyler, J. Chem. Soc., Chem. Commun., 1981, 691 DOI: 10.1039/C39810000691
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