Irradiation of solid solutions of Me3Si–SiMe3 and Me3Ge–GeMe3 in CCl3F by γ-rays generates he organo-metallic radical cations whose e.s.r. parameters establish that the unpaired electron is localized in a σ-bonding orbital between the two metal atoms.
J. T. Wang and F. Williams, J. Chem. Soc., Chem. Commun., 1981, 666 DOI: 10.1039/C39810000666
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