Reaction of some αβ-unsaturated ketones with palladium(II) chloride and sodium carbonate in tetra-hydrofuran (THF) gives acetylacetonate complexes; use of 18O-enriched carbonate shows that the reaction involves a highly unusual transfter of oxygen from carbonate ion to the organic ligand.
P. S. Elmes, G. D. Fallon, B. M. K. C. Gatehouse, W. R. Jackson, A. Stragalinou and B. O. West, J. Chem. Soc., Chem. Commun., 1981, 661 DOI: 10.1039/C39810000661
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