Issue 13, 1981

closo-Carbametallaboranes from direct insertion into nido-carbaboranes: the molecular structures of [6,6-(Et3P)2-1,2,6-C2CoB7H9] and [1,1-(Et3P)2-1,2,4-CoC2B8H10]

Abstract

Reaction of [Co(PEt3)4] with nido-4,5-C2B7H11 and nido-5,6-C2B8H12 affords the wine-red compound closo-[6,6-(Et3P)2-1,2,6-C2CoB7H9] and the purple compound closo-[1,1-(Et3P)2-1,2,4-CoC2B8H10], respectively, both products being structurally characterised by single-crystal X-ray diffraction studies.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 652-653

closo-Carbametallaboranes from direct insertion into nido-carbaboranes: the molecular structures of [6,6-(Et3P)2-1,2,6-C2CoB7H9] and [1,1-(Et3P)2-1,2,4-CoC2B8H10]

G. K. Barker, M. P. Garcia, M. Green, G. N. Pain, F. G. A. Stone, S. K. R. Jones and A. J. Welch, J. Chem. Soc., Chem. Commun., 1981, 652 DOI: 10.1039/C39810000652

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