SCHEDULED MAINTENANCE
Thermal isomerisation of N-allyl-2-oxidoani-linium ylides under mild conditions yields three products which are each formed by two types of competitive pathways; the minor pathway involves a radical pair intermediate and three modes of coupling, and the major pathway involves a collection of concerted sigmatropic rearrangements.
W. D. Ollis, R. Somanathan and I. O. Sutherland, J. Chem. Soc., Chem. Commun., 1981, 573 DOI: 10.1039/C39810000573
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