Issue 11, 1981

Cationic cyclization reactions of 6-methylhept-5-en-2-one oxime; X-ray crystal structure of 3-isopropylidene-2-methyl-Δ1-pyrroline

Abstract

The heterolytic cleavage of the nitrogen-oxygen bond of 6-methyl-hept-5-en-2-one oxime under various conditions has led to two types of cationic cyclization reactions producing Δ1-pyrrolines whose structures have been proved by 13C n.m.r. spectroscopy and X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 568-569

Cationic cyclization reactions of 6-methylhept-5-en-2-one oxime; X-ray crystal structure of 3-isopropylidene-2-methyl-Δ1-pyrroline

R. E. Gawley, E. J. Termine and K. D. Onan, J. Chem. Soc., Chem. Commun., 1981, 568 DOI: 10.1039/C39810000568

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