Intramolecular N-nitrene addition in 2-(hepta-1,6-diene-4-yl)-3-aminoquinazolone derivatives gives aziridines stereospecifically in good yield; the regio-specificity (or lack of it) is rationalised in terms of a non-concerted addition proceeding by electrophilic attack of the nitrene on the alkene double bond via a 7-membered transition state.
R. S. Atkinson, J. R. Malpass, K. L. Skinner and K. L. Woodthorpe, J. Chem. Soc., Chem. Commun., 1981, 549 DOI: 10.1039/C39810000549
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