Issue 11, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

An octanuclear iridum carbonyl cluster based on two equivalent tetrahedral units. Synthesis and X-ray characterization of bis(tetraphenylphosphonium) hexa-µ-carbonylhexadecacarbonyl-ditetrahedro-octairidate (2–)

Francesco Demartin,   Mario Manassero,   Mirella Sansoni,   Luigi Garlaschelli,   Carlo Raimondi C.,   Secondo Martinengo  and  Franco Canziani  

Abstract

The reaction of Ir4(CO)12 with KOH in 1,2-dimethoxyethane, under nitrogen, yields the [Ir8(CO)22]2– anion, which has been shown by X-ray crystallography to contain an iridium double cluster based on two symmetry-equivalent tetrahedral subunits.

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Article information

DOI
https://doi.org/10.1039/C39810000528
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 528-529

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An octanuclear iridum carbonyl cluster based on two equivalent tetrahedral units. Synthesis and X-ray characterization of bis(tetraphenylphosphonium) hexa-µ-carbonylhexadecacarbonyl-ditetrahedro-octairidate (2–)

F. Demartin, M. Manassero, M. Sansoni, L. Garlaschelli, C. Raimondi C., S. Martinengo and F. Canziani, J. Chem. Soc., Chem. Commun., 1981, 528 DOI: 10.1039/C39810000528

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