Issue 11, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

A novel stereoselective route to cis-olefins via addition of vinyl cuprates to αβ-unsaturated sulphones and subsequent desulphonylation

Gioacchino De Chirico,   Vito Fiandanese,   Giuseppe Marchese,   Francesco Naso  and  Oronzo Sciacovelli  

Abstract

Dialkenylcuprates, generated by addition of dialkylcuprates to acetylene, react with αβ-unsaturated sulphones to give cis-γδ-unsaturated sulphones which can be easily desulphonylated with retention of the double-bond configuration.

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Article information

DOI
https://doi.org/10.1039/C39810000523
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 523-524

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A novel stereoselective route to cis-olefins via addition of vinyl cuprates to αβ-unsaturated sulphones and subsequent desulphonylation

G. De Chirico, V. Fiandanese, G. Marchese, F. Naso and O. Sciacovelli, J. Chem. Soc., Chem. Commun., 1981, 523 DOI: 10.1039/C39810000523

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