Issue 11, 1981

An unusual bonding mode for a dithiocarboxylate ligand: a tetradentate interaction; X-ray crystal structure of the product of the reaction of nonacarbonyldi-iron with 1,2-benzodithiole-3-thione

Abstract

The compound 1,2-benzodithiole-3-thione (1), on reaction with Fe2(CO)9, incorporates two Fe2(CO)6 units giving complex (2), the structure of which has been determined by X-ray crystallography; it contains a novel tetradentate RCS2 ligand possessing an iron–carbon bond.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 513-514

An unusual bonding mode for a dithiocarboxylate ligand: a tetradentate interaction; X-ray crystal structure of the product of the reaction of nonacarbonyldi-iron with 1,2-benzodithiole-3-thione

P. H. Bird, U. Siriwardane, A. Shaver, O. Lopez and D. N. Harpp, J. Chem. Soc., Chem. Commun., 1981, 513 DOI: 10.1039/C39810000513

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