Issue 10, 1981

CIDNP from a 1,4-biradical in the norrish type II photoreaction of valerophenone

Abstract

Biradical CIDNP observed in the title reaction indicates that two intersystem-crossing mechanisms are operative in the intermediate 1,4-biradical, one involving hyperfine coupling of the odd electrons with protons and the other, which is product selective, involving spin–orbit coupling.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 499-501

CIDNP from a 1,4-biradical in the norrish type II photoreaction of valerophenone

R. Kaptein, F. J. J. de Kanter and G. H. Rist, J. Chem. Soc., Chem. Commun., 1981, 499 DOI: 10.1039/C39810000499

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