Issue 10, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis of di-rhodium complexes containing s-cis-bridging 1,3-diene ligands: X-ray crystal and molecular structure of µ-(η4-cyclohexa-1,3-diene)-µ-carbonyl-bis-(η5-indenyl)dirhodium(Rh–Rh)

Yassin N. Al-Obaidi,   Michael Green,   Nicholas D. White,   Jean-Marie Bassett  and  Alan J. Welch  

Abstract

Reaction of [Rh3(µ-CO)3(η5-C9H7)3] with buta-1,3-diene, trans-penta-1,3-diene. isoprene, trans, trans- hexa-2,4-diene, cyclopentadiene, and cyclohexa-1,3-diene affords the stable complexes [Rh2(µ-CO)(µ-1,3-diene)(η5C9H7)2]; an X-ray crystallographic study of the cyclohexa-1,3-diene complex shows that the diene is more weakly held than in mononuclear systems.

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Article information

DOI
https://doi.org/10.1039/C39810000494
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 494-496

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Synthesis of di-rhodium complexes containing s-cis-bridging 1,3-diene ligands: X-ray crystal and molecular structure of µ-(η4-cyclohexa-1,3-diene)-µ-carbonyl-bis-(η5-indenyl)dirhodium(Rh–Rh)

Y. N. Al-Obaidi, M. Green, N. D. White, J. Bassett and A. J. Welch, J. Chem. Soc., Chem. Commun., 1981, 494 DOI: 10.1039/C39810000494

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