Both the macro-rings in the double-looptitle ligand, which has C2 symmetry, bind one of the water molecules of solvation and an Li+ ion in the same cavity; the metal ion interacts simultaneously with both captured and the free molecules of water of solvation.
M. Czugler and E. Weber, J. Chem. Soc., Chem. Commun., 1981, 472 DOI: 10.1039/C39810000472
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