Reaction of [{Rh(CO)2Cl2] with PPh2H in benzene produces a unique ‘56 electron’ closed trinuclear rhodium cluster derivative [Rh3(µ-PPh2)3(µ-Cl)2(µ-CO)-(CO)3], in which each rhodium–rhodium edge is bridged by a diphenylphosphino-ligand as well as by either a chloro- or carbonyl group.
R. J. Haines, N. D. C. T. Steen and R. B. English, J. Chem. Soc., Chem. Commun., 1981, 407 DOI: 10.1039/C39810000407
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