Issue 8, 1981

The induced kinetic isotope effect as a tool for mechanistic discrimination

Abstract

Conditions are described under which an isotope effect on the rate of formation of one reaction product can induce an apparent isotope effect on the label distribution in a second product; reaction of trans-2,3-diphenylmethylene [2-2H1] cyclopropane with Fe2(CO)9 serves to illustrate the utility of the method.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 354-356

The induced kinetic isotope effect as a tool for mechanistic discrimination

A. G. Samuelson and B. K. Carpenter, J. Chem. Soc., Chem. Commun., 1981, 354 DOI: 10.1039/C39810000354

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