The first accurate direct measurements of electron exchange rates of cobalt (III)-cobalt(II) tetra-phenylporphyrins indicate rate constants of 9·69 dm3 mol–1s–1[outer-sphere for bis(pyridine) complexes] and 2·71 × 104dm3 mol–1s–1(chloride-bridged inner-sphere) in CDCl3.
R. D. Chapman and E. B. Fleischer, J. Chem. Soc., Chem. Commun., 1981, 332 DOI: 10.1039/C39810000332
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