Issue 7, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

A new bridging geometry for sulphur dioxide in [Mo(CO)2(PPh3)-(pyridine)(µ-SO2)]2·2CH2Cl2; X-ray crystal structure

Gordon D. Jarvinen,   Gregory J. Kubas  and  R. R. Ryan  

Abstract

In CH2Cl2 solution the complex cis, trans-Mo(CO)2(PPh3)2(pyridine)(η2-SO2)(1) reacts to give a dinuclear complex (2); an X-ray crystal structuree determination shows that the moly-bdenum atoms are bridged by two SO2 ligands that are co-ordinated to one metal through the sulphur atom and one oxygen atom and to the second metal via thee remaining oxygen atom.

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Article information

DOI
https://doi.org/10.1039/C39810000305
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 305-306

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A new bridging geometry for sulphur dioxide in [Mo(CO)2(PPh3)-(pyridine)(µ-SO2)]2·2CH2Cl2; X-ray crystal structure

G. D. Jarvinen, G. J. Kubas and R. R. Ryan, J. Chem. Soc., Chem. Commun., 1981, 305 DOI: 10.1039/C39810000305

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