13  C n.m.r. spectra of highly 13CO-enriched metal carbonyls: observation of 2Jcccis coupling constants

Silvio Aime; Domenico Osella

doi:10.1039/C39810000300

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

¹³C n.m.r. spectra of highly ¹³CO-enriched metal carbonyls: observation of ²J_cccis coupling constants

Silvio Aime and Domenico Osella

Abstract

¹³ C N.m.r. spectra of metal carbonyls (>60%¹³CO-enriched) allow the first observation of ²J_CCcis values which are an order of magnitude smaller than ²J_CCtrans; this technique is also useful in the assignment of CO resonances as is shown in the case of H₂Os₃(CO)₁₀.

Download options Please wait...

Article information

DOI: https://doi.org/10.1039/C39810000300
Article type: Paper

Download Citation

J. Chem. Soc., Chem. Commun., 1981, 300-302

Permissions

Request permissions

¹³ C n.m.r. spectra of highly ¹³CO-enriched metal carbonyls: observation of ²J_cccis coupling constants

S. Aime and D. Osella, J. Chem. Soc., Chem. Commun., 1981, 300 DOI: 10.1039/C39810000300

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Fetching data from CrossRef.
This may take some time to load.

Journal of the Chemical Society, Chemical Communications