A single-crystal X-ray structural analysis of the binuclear species [(η5-C5Me4Et) TaCl2]2(µ-H)(µ-CHO) bas been carried out; this molecule contains a ‘side-on’ bridging formyl group in which interatomic distances are Ta(1)-C(1) 2·085(12), Ta(2)-C(1) 2·119(11), Ta(1)-O 2·094(8), Ta(2)-O 2·089(9), and C-O 1·496(14)Å.
M. R. Churchill and H. J. Wasserman, J. Chem. Soc., Chem. Commun., 1981, 274 DOI: 10.1039/C39810000274
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