In hydrocarbon solvents, W2(NMe2)6 and the alcohols MeOH and EtOH react to give W4(OR)16 compounds; the ethoxide adopts a structure akin to that of [Ti(OEt)4]4, but with distortions due to M–M bonds which arise from the presence of the four tungsten d2 ions.
M. H. Chisholm, J. C. Huffman and J. Leonelli, J. Chem. Soc., Chem. Commun., 1981, 270 DOI: 10.1039/C39810000270
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