The first examples of co-ordination complexes containing a phospha-alkene are described; n.m.r. studies on cis-M(CO)4L2(M = Cr,Mo,W), trans-RhCl-(PPh3)2L, trans-RhCIL2(CO), Rh(η5-C9H7)L2, cis-PtX2L2(X = Cl,I,Me), and cis- and trans-PtCl2(PEt3)L, [L = P(mesityl)![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
CPh2], suggest that co-ordination to the metal is via the phosphorus lone pair.
H. Eshtiagh-Hosseini, H. W. Kroto, J. F. Nixon, M. J. Maah and M. J. Taylor, J. Chem. Soc., Chem. Commun., 1981, 199 DOI: 10.1039/C39810000199
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