SCHEDULED MAINTENANCE
In aqueous dimethylformamide solution meso-αααα-tetra(o-maleamoylphenyl)porphyrin undergoes rapid metal incorporation (CuII, ZnII, CoII, and NiII) by a mechanism featuring rate-determining intramolecular transfer of the metal ion from the carboxylate binding site to the porphyrin nucleus.
D. A. Buckingham, C. R. Clark and W. S. Webley, J. Chem. Soc., Chem. Commun., 1981, 192 DOI: 10.1039/C39810000192
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