A π-allyltitanium complex with a chiral cyclo-pentadienyl ligand reacts with carbon dioxide under mild conditions to form a carbon–carbon bond, thus providing that first demonstration of asymmetric carbon dioxide fixation.
F. Sato, S. Iijima and M. Sato, J. Chem. Soc., Chem. Commun., 1981, 180 DOI: 10.1039/C39810000180
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