Issue 4, 1981

Intramolecular reactions of N-nitrenes: oxidation of 3-amino-2-(arylalkyl)quinazolones

Abstract

Oxidation of the title compounds yields N-nitrenes which rect intramolecularly with electron-rich aryl groups via 7-membered transition states; substituent effects are in accord with an electrophilic aromatic substitution rather than concerted addition.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 160-162

Intramolecular reactions of N-nitrenes: oxidation of 3-amino-2-(arylalkyl)quinazolones

R. S. Atkinson, J. R. Malpass and K. L. Woodthorpe, J. Chem. Soc., Chem. Commun., 1981, 160 DOI: 10.1039/C39810000160

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