If the photosensitized (electron transfer) dimerization of 1,1-diphenylethylene or cross-cycloaddition of 1,1-diphenylethylene with methylpropene is carried out in the presence of acrylonitrile or methyl acrylate, alkylated tetrahydronaphthalenes are obtained, consistent with trapping of the intermediate triene via an ‘ene’ reaction.
D. R. Arnold, R. M. Borg and A. Albini, J. Chem. Soc., Chem. Commun., 1981, 138 DOI: 10.1039/C39810000138
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