The isomerization of 5-, 6-, and 7-membered 1,3-dioxacycloalkanes to esters on various metal catalysts is reported, the hydrogenolysis pattern for this type of compound is determined, and a new reaction mechanism is proposed to interpret these catalytic processes.
M. Bartók and J. Czombos, J. Chem. Soc., Chem. Commun., 1981, 106 DOI: 10.1039/C39810000106
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