Maxima are observed in Grunwald–Winstein plots for the solvolyses of methyl perchlorate in aqueous acetone and aqueous dioxan; they may be associated with the unusual solvation characteristics of the perchlorate ion.
D. N. Kevill and A. Wang, J. Chem. Soc., Chem. Commun., 1981, 83 DOI: 10.1039/C39810000083
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