Issue 3, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

Nucleophilic attack on a ligand as a pre-requisite for ligand replacement. Kinetics and mechanism of the replacement of PMe2Ph by P(OMe)3 in [Ru(S2CH)(PMe2Ph)3{P(OMe)3}]+

Terence V. Ashworth,   Dirk J. A. de Waal  and  Eric Singleton  

Abstract

Kinetic data reveal that nucleophilic attack of added PMe2Ph on the dithioformato carbon atom of the title complex catalyses the substitution of PMe2Ph by P(OMe)3to give [Ru(S2CH)(PMe2Ph)2{P(OMe)3}2]+; the structure of one of the intermediates is inferred from the isolation of [Ru{S2C(H)PMe2Ph}(PMe2Ph)2{P(OMe)2Ph}]+.

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Article information

DOI
https://doi.org/10.1039/C39810000078
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 78-79

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Nucleophilic attack on a ligand as a pre-requisite for ligand replacement. Kinetics and mechanism of the replacement of PMe2Ph by P(OMe)3 in [Ru(S2CH)(PMe2Ph)3{P(OMe)3}]+

T. V. Ashworth, D. J. A. de Waal and E. Singleton, J. Chem. Soc., Chem. Commun., 1981, 78 DOI: 10.1039/C39810000078

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