Tricyclo [3.2.1.02,7]octan-6-ones and tricyclo-[2.2.1.02,6]heptan-3-ones are formed in one step from αβ-cyclohexenones and αβ-cyclopentenones, respectively, by treatment of their α′enolates with nitroethene and 1-nitropropene in tetrahydrofuran and then refluxing the resulting solution with added hexamethylphosphoric trimide.
R. M. Cory, P. C. Anderson, F. R. McLaren and B. R. Yamamoto, J. Chem. Soc., Chem. Commun., 1981, 73 DOI: 10.1039/C39810000073
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