Issue 3, 1981

Interconversion of carbocations, free radicals and carbanions in nitroxide solutions

Abstract

Both triphenylmethyl anions and cations are converted into triphenylmethyl radicals when dissolved in solutions containing di-t-butyl nitroxide; when oxygen is admitted both solutions yield triphenylmethylperoxyl radicals, but in the carbocation system the nitroxide is decomposed while in the carbanion system it is regenerated.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 70-71

Interconversion of carbocations, free radicals and carbanions in nitroxide solutions

H. Singh and J. M. Tedder, J. Chem. Soc., Chem. Commun., 1981, 70 DOI: 10.1039/C39810000070

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