15 N and 195Pt n.m.r. studies show that when acetamide is added to aqueous solutions of cis-[Pt(NH3)2-(H2O)2]2+ and [Pt(en)(H2O)2]2+(en = ethylenediamine), equilibria are rapidly established with species in which H2O is substituted by the amide carbonyl oxygen atom without NH2 deprotonation; the relevance to platinum blue formation is discussed.
S. J. S. Kerrison and P. J. Sadler, J. Chem. Soc., Chem. Commun., 1981, 61 DOI: 10.1039/C39810000061
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