In aqueous sodium sulphite solutions, 2,4,6-trinitrotoluene and 2,4,6-trinitrobenzyl chloride give 1 : 1 and 1 : 2 adducts by addition at unsubstituted ring positions. Rate and equilibrium data for these reactions have been obtained by the stopped-flow method and are compared with similar data for other nitro-compounds.
D. N. Brooke and M. R. Crampton, J. Chem. Soc., Perkin Trans. 2, 1980, 1850 DOI: 10.1039/P29800001850
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