When reactive radicals are formed in a solvolysis using di-t-butyl nitroxide (DTBNO) as solvent, the radical abstracts hydrogen from unchanged nitroxide forming 2-methyl-2-nitrosopropane which acts as an internally generated spin trap.
H. Singh, J. M. Tedder and J. C. Walton, J. Chem. Soc., Perkin Trans. 2, 1980, 1259 DOI: 10.1039/P29800001259
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