An efficient total synthesis of the title compound (7) was carried out by acetylene-cation cyclisation of a 1-(pent-3-ynyl)perhydro-2-phenanthrol (6) which was prepared from a ring-D-aromatic steroid (1)via Eschenmoser ring-opening of its 13,17a-epoxy-17-oxo-derivative (3).
T. Kametani, K. Suzuki and H. Nemoto, J. Chem. Soc., Perkin Trans. 1, 1980, 2805 DOI: 10.1039/P19800002805
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...