Issue 0, 1980

Stable carbocations. Part 22. Stereochemistry of the deprotonation of ferrocenylalkylium ions, and of the protonation of alkenylferrocenes

Abstract

In the absence of adverse steric effects, ferrocenylalkylium ions of the type FcC+(R)CH(Ph)Me (Fc = ferrocenyl) undergo preferential exo-deprotonation upon reaction with a base and a similar exo-stereoselectivity is associated with protonation of the resulting alkenes FcC(R)[double bond, length half m-dash]C(Ph)Me in trifluoroacetic acid.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1980, 2213-2217

Stable carbocations. Part 22. Stereochemistry of the deprotonation of ferrocenylalkylium ions, and of the protonation of alkenylferrocenes

C. A. Bunton, W. Crawford, N. Cully and W. E. Watts, J. Chem. Soc., Perkin Trans. 1, 1980, 2213 DOI: 10.1039/P19800002213

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