Issue 0, 1980

Reactions of halogenomethanes in the vapour phase. Part 4. The reactions of imidazoles with chloroform at 550 °C, and a comparison with their liquid-phase reactions with trichloroacetate ion or hexachloroacetone and base

Abstract

1-Unsubstituted imidazoles and chloroform at 550 °C in a flow system give mainly 5-chloropyrimidines, together with 4-chloropyrimidines and chloropyrazines. The effects of methyl substituents on the ratio of products is considered. The liquid-phase reactions of 2-methyl- and 2,4,5-trimethyl-imidazole under conditions in which dichlorocarbene is said to be formed in basic or neutral conditions were studied, and compared with the gas-phase reactions with chloroform.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1980, 1427-1430

Reactions of halogenomethanes in the vapour phase. Part 4. The reactions of imidazoles with chloroform at 550 °C, and a comparison with their liquid-phase reactions with trichloroacetate ion or hexachloroacetone and base

R. E. Busby, M. A. Khan, M. R. Khan, J. Parrick, C. J. G. Shaw and M. Iqbal, J. Chem. Soc., Perkin Trans. 1, 1980, 1427 DOI: 10.1039/P19800001427

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