α-Nitrosulphides were prepared by SRN1 reaction of 2-bromo-2-nitropropane with thiolate anions, and by SN2 attack of sodium 2-nitropropan-2-ide on symmetrical disulphides. The α-nitrosulphides undergo radicalnucleophilic substitution (SRN1) by nitronate, sulphinate, and malonate anions, but not by thiolate anions.
W. R. Bowman and G. D. Richardson, J. Chem. Soc., Perkin Trans. 1, 1980, 1407 DOI: 10.1039/P19800001407
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