Reactions of 3a-7a-dihydroindenones or 3a,4,7,7a-tetrahydro-4,7-methanoindene-1,8-diones with Fe(CO)5 afford indanones as the sole products. No corresponding diene–Fe(CO)3 complexes have been detected. The mechanisms for these reactions are established on the basis of deuterium-labelling experiments.
T. Luh, C. H. Lai and S. W. Tam, J. Chem. Soc., Perkin Trans. 1, 1980, 444 DOI: 10.1039/P19800000444
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