A possible model for a new chiral glyceride synthesis. Part 2. Synthesis of 1,3-di-O-aroyl- and 1-O-aroyl-3-O-tosyl-sn-glycerols from 2,5-O-methylene-D-mannitol
Abstract
1,3-Di-O-aroyl- and 1-O-aroyl-3-O-tosyl-sn-glycerols have been prepared from D-mannitol via 2,5-O-methylene-D-mannitol. Some 1,3-diglycerides have also been synthesised from 3-O-aroyl-sn-glycerols. The optical rotations and the structure of the 1,3-diglycerides have also been confirmed.