The equation of state devised by Redlich and Kwong has been used to predict liquid–vapour equilibria of a pure substance and of mixtures. Predictions have been compared with experiment and with the predictions of other van der Waals-like equations of state. The Redlich–Kwong equation predicts a shape for the critical locus not previously known, corresponding to a closed miscibility gap in the gas region.
K. Stead and J. M. Williams, J. Chem. Soc., Faraday Trans. 2, 1980, 76, 1045 DOI: 10.1039/F29807601045
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