The specific ionic adsorption equilibrium at the metal–solution interface is described in terms of the Stern–Grahame model of the double layer. The use of transference numbers in the description of the diffuse layer allows the correct concentration variable to be employed when applying the formalism of the adsorption isotherm to specifically adsorbed ions in the compact layer.
D. Posadas, J. Chem. Soc., Faraday Trans. 1, 1980, 76, 1633 DOI: 10.1039/F19807601633
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